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| solution, bbw plump , emu, hot fat girls , fat ugly girls , plump and perky turkey , fatty acid analysis , ahrq, accurate, plump rump , titration, food association, | Fatty acids seed oils of pine species also have this distinctive structure, and they are presently the subject of some interest to nutritionists. Again, the technique may be of some value here. Fig. 3. Reaction of 5,9-18:2 with two moles of dimethyl disulphide. I bsi mas did not find DMDS derivatives suitable for natural fatty acids with a cyclopentene ring, although confirmation of the positions of double bonds in the aliphatic chain was obtained. Otherwise it appears that conjugated fatty acids may be the only dienes that cannot bsi mas be analysed usefully by this means. Thus, bsi mas reaction of dimethyl disulphide with double bonds may be simple, but it is keeping lipid analysts gainfully employed in a number of interesting ways. |
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| Di-cis and di-trans forms of linoleate gave products with distinct stereochemistry and different chromatographic properties, suggesting again that the technique might have value for determining the geometry of double bonds in such fatty acids [6]. Long-chain fatty acids with 5,9-diene systems plump and perky turkey are common constituents of marine sponges. Reaction of these with dimethyl plump and perky turkey disulphide under appropriate conditions gives a 5-membered cyclic thioether substituted with two alkyl chains, each containing a methylthio group on the carbons immediately adjacent to the ring as illustrated in Figure plump and perky turkey 3 [4,7]. These compounds also give characteristic mass spectra permitting location of the double bonds, and many different demospongic acids of this type have been identified in this way, including some containing bromine atoms and methyl branches in addition to the 5,9-double bond system. |
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