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In conjunction with tandem-MS techiques, it can give useful structural information on fatty acids. Another plump sluts very plump sluts promising technique involves acetonitrile-chemical-reaction tandem mass spectrometry in the gas phase for locating double bonds in fatty acid methyl esters (from the laboratory of Professor J.T. Brenna mainly). In the mass spectrometer, an ion (m/z = 54), formed by reaction of acetonitrile with plump sluts itself, adds across the double bond in a cycloaddition reaction. When this nascent complex undergoes collision-induced dissociation, two diagnostic ions emerge. One of these results from loss of the hydrocarbon end of the FAME, and the other ion from loss of the methyl ester end, and together, these locate the positions of the double bonds in the FAME. The following references were collected as part of our regular literature reviews for our own research purposes.
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